Advances in Controlled/Living Radical Polymerization - download pdf or read online

By Krzysztof Matyjaszewski

ISBN-10: 0841219591

ISBN-13: 9780841219595

ISBN-10: 0841238545

ISBN-13: 9780841238541

Provides new advancements in controlled/living radical polymerization in 3 components: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally contains synthesis and characterization of many new materials.

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Murata, Y . ; Fukuda, T. Macromolecules 2002, 35, 3026. Kwak, Y . , to be published. Hui, A. ; Hamielec, A. E. J. Appl. Polym. 19 72, 16, 749. Molnar, S. J. Polym. , Part A-1 1972,10 , 2245. Gilbert, R. G. Pure Appl. Chem. 1996,68 , 1491. ; Fukuda, T. Macromol. Chem. Phys. 2000, 201, 2138. Ohno, K . ; Matyjaszewski, K . Macromolecules 1998, 31, 2699. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2003. de Termination kinetics of acrylate and methacrylate homo- and copolymerizations at 40°C and 1000 bar have been measured up to high conversion via the S P - P L P technique.

W. C. 20036 ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 48 The data points exhibit some cluster-type structure which is due to the slight variation OÎ/ÔMA with X that allows for deducing &,copo at (slightly) different/DMA from successive S P - P L P experiments carried out during one copolymerization experiment at increasing X. The log vs. / D M A correlation is curved for D M A - Μ Α and thus differs from the corresponding close-to-linear relation observed with the intra-family D A - M A system (dotted line in Figure 2) (6, 7).

The other is the cross-termination between the intermediate and the linear radical P* with a rate constant ft comparable in magnitude to k (cf. Scheme 2b). This assumption led to an estimate of k of about 10 s" (73). Between these two estimates of fc is a difference of 7 orders of magnitude. 08) and initiated by the conventional initiator AlBN (14). Figure 5 shows the result of a series of kinetic analyses. 45 in the presence of the RAFT agent than in its absence (Figure 5b). The concentration of the intermediate radical P-(X*)-P was determinable by ESR.

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Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

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